Dissolved sulfate δ <sup>34</sup> S and the origin of sulfate in coal mine waters; NE England
نویسندگان
چکیده
Coal mine waters have been sampled during a reconnaissance study in the East Midlands, South Yorkshire and Tyneside areas of England. Almost all had similar δ 18 O 2 H concentrations, indicating derivation from Holocene recharge (average −7.9 −54‰, respectively, excluding two outliers). Most emerging by shallow gravity drainage dissolved sulfate 34 S levels <+10‰, suggesting oxidation pyrite. Deeper waters, pumped boreholes or shafts, tended to be more saline with >+14‰ and, cases, >+30‰. The these latter cannot readily explained as deriving pyrite oxidation. Alternative hypotheses (evaporitic marine brines, evaporite dissolution partially-closed-system microbial reduction) can invoked explanations. A general hypothesis proposes that deep groundwaters/mine regarded ‘sinks’, whose concentration is controlled dynamic equilibrium between rates mobilization various sources removal precipitation reduction. Supplementary material : Material (a detailed description sample sites results) B (locations sites) are available at https://doi.org/10.6084/m9.figshare.c.6418981
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ژورنال
عنوان ژورنال: Quarterly Journal of Engineering Geology and Hydrogeology
سال: 2023
ISSN: ['2041-4803', '1470-9236']
DOI: https://doi.org/10.1144/qjegh2022-106